研究業績

1995〜1996年

1997〜1998年

1999〜2000年

2001〜2002年

2003〜2004年

2007〜2008年

論文

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Miyagishi S., Kurimoto H., Asakawa T.,
Microviscosity and Micellar Phase Diagrams Determined with Fluorescence Probes. Bull. Chem, Soc. Jpn., 1995, 68(1), 135.

Asakawa T., Hisamatsu H., Miyagishi, S.,
Micellar Pseudophase Separetion Reagions of 1H,1H,2H,2H-Perfluoroalkylpyridinium Chloride and Hydrocarbo Surfactants by Group Contribution Method. Langmuir, 1995, 11(2), 478.

Asakawa T., Hashikawa M., Amada K., Miyagishi, S.,
Effect of Urea on Micelle Formation of Fluorocarbon Surfactants. Langmuir,
1995, 11(7), 2376

Miyagishi S., Kurimoto H., Asakawa T.,
Microviscosity of Sodium N-Acylvalinate Micelles on Sodium Chloride Solution. Langmuir, 1995, 11(8), 2951.

Asakawa T., Shiraishi T., Sunazaki S. Miyagishi, S.,
Critical Demicellization Concentration of Diethylammonium Perfluorononanoate
and Diethylammonium Tetradecyl Sulfate Mixture in Aqueous Solution. Bull.
Chem. Soc. Jpn.
, 1995, 68(9), 2503

Vlasov A. Y, Miyagishi S., On polymorphic transitions of micellar aggregates in salt-aqueous solutions of N-acylamino acids, Izvestia Rossijskoi Akademii Nauk, Ser, Phy., 59 (3), 21〜30 (1995)

Asakawa T., Ikehara J., Miyagishi, S.,
Solubilization of Octafluoronaphthalene by Mixed Micelles of Fluorocarbon
and Hydrocarbon Surfactants in Aqueous Solutions. J. Am. Oil Chem. Soc.,
1996, 73(1), 21

Miyagishi S., Akasofu W., Hashimoto T., Asakawa T.,
Effect of NaCl on Aggregation Number, Microviscosity, and cmc of N-Dodecanoyl Amino Acid Surfactant Micelles. J. Colloid Interface Sci., 1996, 184, 527.

Asakawa T., Hisamatsu H., Miyagishi, S.,
Experimental Verification of Demixing Micelle Composed of Fluorocarbon and
Hydrocarbon Surfactants via Fluorescence Quenching Method. Langmuir, 1996,
12(5), 1204

Miyagishi S., Suzuki H., Asakawa T.,
Microviscosity and Aggregation Number of Potassium N-Acylalaninate Micelles on Potassium Chloride Solution. Langmuir, 1996, 12(12), 2900.

論文

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Asakawa T., Okamoto T., Miyagishi, S.,
Pyrene Fluorescence-quenching by 1,1,2,2-Tetrahydroheptadecafluorodecyl Pyridinium Chloride in Mixed, Fluorocarbon and Hydrocarbon, Micelles. J. Jpn. Oil Chem. Soc., 1997, 46(7), 777.


Almgren M., Wang K., Asakawa T.,
Fluorescence quenching studies of micellisation and solubilization in fluorocarbon-hydrocarbon surfactant mixtures. Langmuir, 1997, 13(17), 4535.

Asakawa T., Saruta A., Miyagishi, S.,
Distribution of Fluorocarbon Quencher among Micelles via Pyrene Fluorescence Probe Method.
Colloid Polymer Sci. 1997, 275(10), 958.

Asakawa T., Amada K., Miyagishi, S.,
Micellar Immiscibility of Lithium 1,1,2,2-Tetrahydroheptadecafluorodecyl Sulfate and Lithium Tetradecyl Sulfate Mixture. Langmuir, 1997, 13(17), 4569.

Aratono M., Ohta A., Ikeda N., Matsubara A., Motomura K., Takiue T.
Calorimetry of Surfactant Solutions. Measurement of the Enthalpy of Mixing of Tetraethylene Glycol Monooctyl Ether and Water, J. Phys. Chem. B, 1997, 101(18), 3535.

Asakawa T., Kitaguchi T., Miyagishi, S.,
Synergistic Solubilization of Decafluorobiphenyl by Micelles of Fluorocarbon Surfactants. J. of Surfactants & Detergents. 1998, 1(2), 195.

Asakawa T., Sunagawa H., Miyagishi, S.,
Diffusion Coefficient of Micelles composed of Fluorocarbon Surfactants with Cyclic Voltammetry.
Langmuir, 1998, 14(25), 7091.

Ohta A., Takiue T., Ikeda N., Aratono M.
Calorimetric Study of Dilute Aqueous Solutions of Ethylene Glycol Oligomers
J. Phys. Chem. B, 1998, 102(24), 4809.

総説・報告書
宮岸重好、アミノ酸系界面活性剤のミセル状態−蛍光プローブ法でどこまで迫れるか−表面、35(2), pp.85, (1997.2).

浅川 毅、ミクロ相分離一分子巨大ミセルの創成と蛍光発光制御,1997年度旭硝子財団助成研究成果報告書、pp.24, (1997.12).

論文

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Asakawa T., Miyagishi, S.,
Demicellization of Sodium Perfluorooctanoate and Dodecyl Sulfate Mixtures Revealed by Pyrene Fluorescence Quenching. Langmuir, 1999,15(10), 3464 .


Wang K., Karlsson G., Almgren M., Asakawa T.,
Aggregation Behavior of Cationic Fluorosurfactants in Water and Salt Solutions. A Cryo-TEM Survey. J. Phys. Chem. B, 1999,103(42), 9237.


Aratono M., Ohta A., Minamizawa, H., Ikeda N., Iyota H., Takiue T.
The Excess Thermodynamic Quantities of Adsorption of a Binary Nonionic Surfactant Mixture. J. Colloid Interface Sci., 1999, 217, 128 .


Matsubara H., Ohta A., Kameda M., Villeneuve M., Ikeda N., Aratono M.
Interaction between Ionic and Nonionic Surfactants in the Adsorbed Film and Micelle. Hydrochloric Acid, Sodium Chloride and Tetraethylene Glycol Monooctyl Ether. Langmuir, 1999,15(17), 5496.


Wang K., Oradd G., Almgren M., Asakawa T., Bergenstahl B.,
Phase Behavior and Phase Structure of a Cationic Fluorosurfactant in Water. Langmuir, 2000,16(3), 1042.


Ohta A., Murakami R., Takiue T., Ikeda N., Aratono M.
Calorimetric Study of Micellar Solutions of Pentaethylene Glycol Monooctyl and Monodecyl Ethers. J. Phys. Chem. B, 2000,104(35), 8592.


Matsubara H., Ohta A., Kameda M., Ikeda N., Aratono M.
Interaction between Ionic and Nonionic Surfactants in the Adsorbed Film and Micelle. Dodecylammonium Chloride and Tetraethylene Glycol Monooctyl Ether. Langmuir, 2000,16(20), 5496.

論文

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Ohta A., Miyagishi S., Aratono M.
Calorimetry of Micelle Formation of Binary Nonionic Surfactant Mixtures. J. Phys. Chem. B, 2001,105(14), 2826.

Ohta A., Matsubara H., Ikeda N., Aratono M.
Miscibility of binary surfactant mixtures in the adsorbed film and micelle: the effect of size of polar head group. Colloids Surf. A, 2001,183-185(1-3), 403.

Ohta A., Takiue T., Ikeda N., Aratono M.
Calotimetric Study of Micelle Formation in Polyethylene Glycol Monooctyl Ether Solutions. J. Solution Chem., 2001, 30(4), 335.

Miyagishi S., Okada K., Asakawa T.
Salt Effect of Critical Micelle Concentrations of Nonionic Surfactant, N-Acyl-N-methylglucamides (MEGA-n). J. Colloid Interface Sci., 2001, 238, 91 .

Davey T. M., Warr G. G., Almgren M., Asakawa T.
Self-Assembly of Hydrocarbon and Fluorocarbon Surfactants and Their Mixtures at Mica-Solution Interface. Langmuir, 2001,17(17), 5283.

Asakawa T., Ishikawa K., Miyagishi S.
Aqueous Solution Properties of Pyridinium-Type Perfluorinated Surfactants and Simulation of Mixture CMC. J. Colloid Interface Sci., 2001, 240, 365.

Asakawa T., Kitano T., Ohta A., Miyagishi S.
Convenient Estimation for Dissociation of Cationic Micelles Using Chloride-Sensitive Fluorescence Probe. J. Colloid Interface Sci., 2001, 242, 284.

Wongwailikhit K., Ohta A., Seno K., Nomura A., Shinozuka T., Takiue T., Aratono M.
Temperature Effect on the Adsorption and Micelle Formation of Pentaethylene Glycol Monoalkyl Ethers. J. Phys. Chem. B, 2001,105(46), 11462.

Matsubara H., Muroi S., Kameda M., Ikeda N., Ohta A., Aratono M.
Interaction between Ionic and Nonionic Surfactants in the Adsorbed Film and Micelle. 3. Sodium Dodecyl Sulfate and Tetraethylene Glycol Monooctyl Ether. Langmuir, 2001,17(25), 7752.

Miyagishi S., Takeuchi N., Asakawa T., Inoh M.
Micellar growth of N-dodecanoyl-alaninates with different counterions and its quantitative relation with some factors. Colloids Surf. A, 2002,197, 125.

Murakami R., Takata Y., Ohta A., Suzuki M., Takiue T., Aratono M.
Calorimetric Studies of Aggregate Formation of Oleyl Alcohol in Oil Solutions. J. Phys. Chem. B, 2002,106,6548.

Ohta A., Matsubara H., Matsukubo T., Takiue T., Ikeda N., Aratono M.
Phase Transition and Miscibility of Binary Surfactant Mixtures in the Adsorbed Film at Air/Water Surface. J. Colloid Interface Sci., 2002, 256, 411.


総説・報告書
浅川 毅、分子集合体系における分子のノンランダム分布,平成10〜12年度科学研究費補助金(基盤研究C)研究成果報告書(2001.3)

浅川 毅、宮岸重好、界面活性剤水溶液のミセル系におけるミクロ相分離,表面、39(4), pp.160, (2001.4).

太田 明雄、池田 宜弘、荒殿 誠、非イオン界面活性剤水溶液の恒温滴定カロリメトリー,熱測定、28(3), pp.144, (2001.6)

論文

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Ohta A., Ozawa N., Nakashima S., Asakawa T., Miyagishi S.
Krafft temperature and enthalpy of solution of N-acyl amino acid surfactants and thier racemic modifications: effect of the amino acid residue. Colloid Polym. Sci., 2003,281, 363.

Miyagishi S., Takagi M., Kadono S., Ohta A., Asakawa T.
Effect of amino acid surfactants on phase transition of poly(N-isopropylacrylamide) gel. J. Colloid Interface Sci., 2003, 261, 191.

Davey T. M., Warr G. G., Asakawa T.
Composition of Mixed Hydrocarbon and Fluorocarbon Surfactant Adsorbed Layers at Mica-Solution Interface. Langmuir, 2003,19(13), 5266-5272.

Ishino S., Asakawa T., Ohta A., Miyagishi S.
Fluorescence Quenching of Quinoline Derivatives in a Micelle System. Journal of Oleo Science, 2003, 52(10), 535-540

Ohta A., Murakami R., Urata A., Asakawa T. Miyagishi S., Aratono M.
Aggregation Behavior of Fluorooctanols in Hydrocarbon Solvents. The Journal of Physical Chemistry B, 2003, 107, 11502-11507

Ohta A., Nakashima S., Matsuyanagi H., Asakawa T., Miyagishi S.
Krafft Temperature and Enthalpy of Solution of N-Acyl Amino Acid Surfactants and Their Racemic Modifications: Effect of Counter Ion. Colloid Polym. Sci., 2003, 282, 162-169.

Murakami R., Takata Y., Ohta A., Takiue T., Aratono M.
Aggregate formation in oil and adsorption at oil/water interface: thermodynamics and its application to the oleyl alcohol system. Journal of Colloid and Interface Science, 2004, 270, 262-269

T. Asakawa, S. Ishino, P. Hansson, M. Almgren, A. Ohta, S. Miyagishi
Appearance of Pure Fluorocarbon Micelles Surveyed by Fluorescence Quenching of Amphiphilic Quinoline Derivatives in Fluorocarbon and Hydrocarbon Surfactant Mixtures.
Langmuir 2004, 20(17), pp6998-7003

S. Areva, C. Boissiere, D. Grosso, T. Asakawa, C. Sanchez, M. Linden
One-pot aerosol synthesis of ordered hierarchical mesoporous core-shell silica nanoparticles
Chem. Comm. 2004, 14, pp1630-1631

T. Asakawa, K. Iriyama, A. Ohta, S. Miyagishi
Micellar Counterion Binding for Alkylpyridinium Iodides Probed by N-Sulfopropylacridinium Fluorescence Quenching.
Journal of Oleo Science, 2004, 4(9), pp445-451

Ohta A., Hata Y., Mizuno Y., Asakawa T., Miyagishi S.
Phase Diagrams of Mixtures of Diastereomeric Salts of N-Acyl Amino Acid-type Surfactants and Separation of Enantiomers.
The Journal of Physical Chemistry B, 2004, 108, 12204-12209

総説・報告書

浅川 毅
油化学辞典−脂質・界面活性剤 丸善 日本油化学会編 分担執筆(2004.3)

論文

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Ohta A, Tani-i K, Hoshiba A, Asakawa T, Miyagishi S
Vesicle-Micelle Transition of N-Acyl Phenylalaninate Salt in Very Dilute Aqueous Solution. Chemistry Letters, 2005, 34(4), 560〜561.

Yasuhara K, Ohta A, Asakura Y, Kodama T, Asakawa T, Miyagishi S
Unique Incorporation Behavior of Amino Acid-Type Surfactant into Phospholipid Vesicle Membrane. Colloid Polymer Science , 2005, 283(8), 987〜993.

Kuwamoto K, Asakawa T, Ohta A, Miyagishi S.
Degree of Micelle Ionization and Micellar Growth for Gemini Surfactants Detected by 6-Methoxy-N-(3-sulfopropyl)quinolinium Fluorescence Quenching. Langmuir , 2005, 21(17), 7691〜7695.

Ozawa T., Asakawa T., Ohta A., Miyagishi S.
Halide-sensitive Fluorescent Probes for Self-assembly of Novel Cationic Fluorosurfactants . Journal of Oleo Science, 2005, 54(3), 135-142

Asakawa T., Ozawa T,. Kubode H., Ohta A., Miyagishi S.
Micellar Counterion Binding Probed by Fluorescence Quenching of 6-methoxy-N-(3-sulfopropyl)quinolonium. Journal of Oleo Science, 2005, 54(10), 545~552

Kodama T, Ohta A, Toda K, Katada T, Asakawa T, Miyagishi S.
Fluorescence Probe Study of Vesicle and Micelle Formations in a Binary Cationic Surfactant Systems. Colloids and Surfaces A, 2006, 277, 20〜26.

Asakawa T, Okada T, Hayasaka T, Kuwamoto K, Ohta A, Miyagishi S
The Unusual Micelle Micropolarity of Partially Fluorinated Gemini Surfactants Sensed by Pyrene Fluorescence
. Langmuir, 2006, 22(14),6053〜6055.

Ohta A., Danev R., Nagayama K., Mita T., Asakawa T., Miyagishi S.
Transition from Nanotubes to Micelles with Increasing Concentration in Dilute Aqueous Solution of Potassium N-Acyl Phenylalaninate. Langmuir, 2006

総説・報告書

Miyagishi S, Asakawa T, Ohta A
Mixed Surfactant Systems Second Edition, Revised and Expanded (Abe M., Scamehorn J. F. eds.),Surfactant Science Ser. Vol.124, 13, p431-476, 2005

太田 明雄
ペプチド間水素結合ネットワークを利用したVOCの固定化,平成14年度向科学技術振興財団 研究成果報告書(2005.1)

太田 明雄
リン脂質ベシクル上にリポアミノ酸が形成するナノチャンネルとその薬物放出能の検討,平成16年度コスメトロジー研究振興財団 研究業績中間報告書(2006.3)

太田 明雄
リポソーム上に形成されるアシルアミノ酸ナノチャンネルの構造評価,文部科学省ナノテクノロジー総合支援プロジェクト 平成17年度支援実績報告書(2006.3)

太田 明雄
アシルアミノ酸塩の物性に及ぼす対イオンの効果 オレオサイエンス, 2006, 6(1), 7〜14

論文

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Barber P., Asakawa T., Christenson H. K., What Determines the Size of Liquid Capillary Condensates Below the Bulk Melting Point?
J. Phys. Chem. C, 2007, 111, 2141-2148

Almgren M., Garamus V. M., Asakawa T., Jiang N.,
Contrast Variation SANS Investigation of Composition Distributions in Mixed Surfactant Micelles. J. Phys. Chem. B, 2007, 111, 7133-7141

Ozawa T., Asakawa T., Ohta A., Miyagishi S.,
New Florescent Probes Applicable to Aggregates of Fluorocarbon Surfactants.  Journal of Oleo Science., 2007, 56 (11), 587-593

Ishibai Y., Sato J., Akita S., Nishikawa T., Miyagishi S.,
Photocatalytic Oxidation of NOx by Pt-Modified TiO2 under Visible Light Irradiation, Ishibai Y.; Miyagishi S., Journal of Photochemistry and Photobiology A: Chemistry, 2007, 188, 106-111

Aratono M., Onimaru, N. Yoshikai Y., Shigehisa M., Koga I., Wongwailikhit K., Ohta A., Takiue T, Lhoussaine B, Strey R., Takata Y., Villeneuve M., Matsubara M.
Spontaneous vesicle formation of single chain and double chain cationic surfactant mixtures. J. Phys. Chem. B, 2007, 111,107~115

Asakawa T. , Shimizu Y. , Ozawa T., Ohta A., Miyagishi S. ,
Aqueous Solution Properties of Disulfide Linked Gemini and Cleaved Monomeric Thiol Surfactants.   Journal of Oleo Science, 2008, 57(4), 243-249

Ishibai Y., Akita J., Sato J., Nishikawa T., Miyagishi S.
Synthesis of visible-light active TiO2 photocatalyst with Pt- modification: Role of TiO2 substrate for high photocatalytic activity
Applied Catalysis B: Enviromental , 2008, 79,117-121

Ohta A., Toda K., Morimoto Y., Asakawa T., Miyagishi S.
Effect of the Side Chain of N-Acyl Amino Acid Surfactants on Micelle Formation: An Isothermal Titration Calorimetry Study. Colloids and Surfaces A 2008, 317, 316~322

Ohta A., Shirai M., Asakawa T., Miyagishi S.
Effect of Stereochemistry on the Molecular Aggregation of Phenylalanine Dipeptide-type Surfactants. Journal of Oleo Science, 2008,57(12), 659-667

総説・報告書

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